Molecular dynamics study of mesophase transitions upon annealing of imidazolium-based ionic liquids with long-alkyl chains

HL Peng and M Kubo and H Shiba, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 20, 9796-9805 (2018).

DOI: 10.1039/c8cp00698a

Molecular dynamics simulations are performed on a 1-dodecyl-3-methylimidazolium hexafluorophosphate (C(12)mimPF6) ionic liquid using a united-atom model. The ionic liquid exhibits second step relaxation at temperatures below a crossover point, where the diffusion coefficient shows an Arrhenius to non-Arrhenius transition. Annealing below this crossover temperature makes an isotropic to mesophase transition, where the smectic A (SmA) phase or crystal-like smectic B (SmB) phase forms. Hundreds of nanoseconds are required for completing these transitions. A normal diffusion process is found for anions along the layer-normal and -lateral directions in the SmA phase, but only in the lateral directions in the SmB phase. We find a preserved orientational order for the imidazolium-ring rotational and the alkyl- chain reorientational dynamics in both of the smectic phases.

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