Unraveling the Polymer Chain-Adsorbed Constrained Interfacial Region on an Atomistically Thin Carbon Sheet

S Kumar and KK Sriramoju and VK Aswal and V Padmanabhan and G Harikrishnan, JOURNAL OF PHYSICAL CHEMISTRY B, 123, 2994-3001 (2019).

DOI: 10.1021/acs.jpcb.8b12577

Confinement of graphene and its functional derivatives in synthetic and biomacromolecules has been widely demonstrated recently to manifest in several multiscale phenomena in their mixtures. However, the intricate adsorbed interfacial region formed between polymer chains and a single layer of atomistically thin carbon sheet hitherto evaded an understanding of its nature and characteristics. Here, we reveal the structure of this constrained region and estimate the thickness of the adsorbed polymer layer on a single layer of an atomistically thin graphene oxide sheet using both direct experiments and molecular dynamics simulations. We use small-angle neutron scattering on a model multicomponent mixture formed by an adsorbing polymer, graphene oxide, and solvent for revealing the structure of the constrained interfacial region. We quantify the intricate adsorbed polymer layer thickness on a single layer of atomistically thin graphene oxide sheet by Euclidean approximation of the experimentally observed self-similar interfacial structure. The state of polymer chain random walk and influence of unadsorbed chains under experimental conditions are investigated and juxtaposed against the accuracy of this quantification. For long-chain polymers, the adsorbed layer thickness increases with increasing polymer molecular weight and shows a scaling relationship delta similar to R-g(0.22) with the polymer radius of gyration. For short-chain polymers, the thickness is nearly independent of molecular weight and shows a scaling relationship delta similar to 0.6R(g)(0.22). Coarse-grained molecular dynamics simulations performed on a model system similar to experiments qualitatively ratify the experimentally observed molecular weight thickness relationship. Simulations show no discernible scaling relationship between radius of gyration and adsorbed layer thickness for low-molecular-weight polymers but show a consistent scaling delta similar to R-g for high molecular-weight polymers. A comparison between results from experiments and simulations indicates a discerning pathway in deciphering interface-governed multiscale phenomena in mixtures of adsorbing macromolecules with graphene and its functional derivatives.

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