Role of ionization fraction on the surface roughness, density, and interface mixing of the films deposited by thermal evaporation, dc magnetron sputtering, and HiPIMS: An atomistic simulation

M Kateb and H Hajihoseini and JT Gudmundsson and S Ingvarsson, JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 37, 031306 (2019).

DOI: 10.1116/1.5094429

The effect of ionization fraction on the epitaxial growth of Cu film on Cu (111) substrate at room temperature is explored. Three deposition methods, thermal evaporation, dc magnetron sputtering (dcMS), and high power impulse magnetron sputtering (HiPIMS) are compared. Three deposition conditions, i.e., fully neutral, 50% ionized, and 100% ionized flux were considered thermal evaporation, dcMS, and HiPIMS, respectively, for similar to 20 000 adatoms. It is shown that higher ionization fraction of the deposition flux leads to smoother surfaces by two major mechanisms, i.e., decreasing clustering in the vapor phase and bicollision of high energy ions at the film surface. The bicollision event consists of local amorphization which fills the gaps between islands followed by crystallization due to secondary collisions. The bicollision events are found to be very important to prevent island growth to become dominant and increase the surface roughness. Regardless of the deposition method, epitaxial Cu thin films suffer from stacking fault areas (twin boundaries) in agreement with recent experimental results. Thermal evaporation and dcMS deposition present negligible interface mixing while HiPIMS deposition presents considerable interface mixing. Published by the AVS.

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