Electrochemical generation of liquid and solid sulfur on two-dimensional layered materials with distinct areal capacities

AK Yang and GM Zhou and X Kong and RA Vila and A Pei and YC Wu and XY Yu and XL Zheng and CL Wu and BF Liu and H Chen and Y Xu and D Chen and YX Li and S Fakra and HY Hwang and J Qin and S Chu and Y Cui, NATURE NANOTECHNOLOGY, 15, 231-+ (2020).

DOI: 10.1038/s41565-019-0624-6

A supercooled liquid phase of elemental sulfur can be grown electrochemically on two-dimensional materials. This phase has a markedly higher areal capacity than solid sulfur, with possible implications for future lithium-sulfur batteries. It has recently been shown that sulfur, a solid material in its elementary form S-8, can stay in a supercooled state as liquid sulfur in an electrochemical cell. We establish that this newly discovered state could have implications for lithium-sulfur batteries. Here, through in situ studies of electrochemical sulfur generation, we show that liquid (supercooled) and solid elementary sulfur possess very different areal capacities over the same charging period. To control the physical state of sulfur, we studied its growth on two-dimensional layered materials. We found that on the basal plane, only liquid sulfur accumulates; by contrast, at the edge sites, liquid sulfur accumulates if the thickness of the two- dimensional material is small, whereas solid sulfur nucleates if the thickness is large (tens of nanometres). Correlating the sulfur states with their respective areal capacities, as well as controlling the growth of sulfur on two-dimensional materials, could provide insights for the design of future lithium-sulfur batteries.

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