Molecular Recognition at Mineral Interfaces: Implications for the Beneficiation of Rare Earth Ores

JE Sutton and S Roy and AU Chowdhury and LL Wu and AK Wanhala and N De Silva and S Jansone-Popova and BP Hay and MC Cheshire and TL Windus and AG Stack and A Navrotsky and BA Moyer and B Doughty and VS Bryantsev, ACS APPLIED MATERIALS & INTERFACES, 12, 16327-16341 (2020).

DOI: 10.1021/acsami.9b22902

Ce-bastnasite is the single largest mineral source for light rare-earth elements. In view of the growing industrial importance of rare-earth minerals, it is critical to develop more efficient methods for separating the valuable rare-earth-containing minerals from the surrounding gangue. In this work, we employ a combination of periodic density functional theory (DFT) and molecular mechanics (MM) calculations together with the de novo molecular design program HostDesigner to identify bis-phosphinate ligands that preferentially bind to the (100) Ce-bastnasite surface rather than the (104) calcite surface. DFT calculations for a simple phosphinate ligand were employed to qualitatively understand key behaviors involved in ligand-metal, ligand-solvent, and solvent-metal interactions. These insights were then used to guide the search for flexible, rigid, and semirigid hydrocarbon linkers to identify candidate bis-phosphinate ligands with the potential to bind preferentially to Ce-bastnasite. Among the five most promising bis-phosphinate ligands suggested by theoretical studies, three ligands were synthesized and their adsorption characteristics to bastnasite (100) interfaces were characterized using vibrational sum-frequency (vSFG) spectroscopy, attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy, and isothermal titration calorimetry (ITC). The efficacy of the selective interfacial molecular binding was demonstrated by identifying a bisphosphinate ligand capable of providing an overall higher surface coverage of alkyl groups relative to a monophosphinate ligand. The results highlight the interplay between adsorption binding strength and maximum surface coverage in determining ligand efficiency to render the mineral surface hydrophobic. DFT calculations further indicate that all tested ligands have higher affinity for Ce-bastnasite than for calcite. This is consistent with the ITC data showing stronger adsorption enthalpy to bastnasite than to calcite, making these ligands promising candidates for selective flotation of Ce-bastnasite.

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