Toward the Prediction and Control of Glass Transition Temperature for Donor-Acceptor Polymers

S Zhang and A Alesadi and M Selivanova and ZQ Cao and ZY Qian and SC Luo and L Galuska and C Teh and MU Ocheje and GT Mason and PBJ St Onge and DS Zhou and S Rondeau-Gagne and WJ Xia and XD Gu, ADVANCED FUNCTIONAL MATERIALS, 30, 2002221 (2020).

DOI: 10.1002/adfm.202002221

Semiconducting donor-acceptor (D-A) polymers have attracted considerable attention toward the application of organic electronic and optoelectronic devices. However, a rational design rule for making semiconducting polymers with desired thermal and mechanical properties is currently lacking, which greatly limits the development of new polymers for advanced applications. Here, polydiketopyrrolopyrrole (PDPP)-based D-A polymers with varied alkyl side-chain lengths and backbone moieties are systematically designed, followed by investigating their thermal and thin film mechanical responses. The experimental results show a reduction in both elastic modulus and glass transition temperature (T-g) with increasing side-chain length, which is further verified through coarse-grained molecular dynamics simulations. Informed from experimental results, a mass-per-flexible bond model is developed to capture such observation through a linear correlation between T-g and polymer chain flexibility. Using this model, a wide range of backbone T-g over 80 degrees C and elastic modulus over 400 MPa can be predicted for PDPP-based polymers. This study highlights the important role of side-chain structure in influencing the thermomechanical performance of conjugated polymers, and provides an effective strategy to design and predict T-g and elastic modulus of future new D-A polymers.

Return to Publications page