Shock wave propagation through air: a reactive molecular dynamics study

S Pal and N Mitra, PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 477, 20200676 (2021).

DOI: 10.1098/rspa.2020.0676

Shock compression of air is observed in numerous situations ranging from explosions to hypersonic vehicle entry into atmosphere. In an effort to develop continuum-based equation of state for air subjected to shock compression, it is necessary to understand the dynamics of the shock compression process with regards to formation of new chemical species in air at the molecular level. With this in perspective, three different models of air (consisting a mixture of O-2, N-2 and CO2 gas, with or without H2O based on presence of humidity) are subjected to shock compression ranging from 0.5kms(-1) to 5.0kms(-1) particle velocities. Thermodynamic quantities are evaluated to plot Rankine Hugoniot planes for the three different air models: dry air at mean sea level (MSL), humid air at MSL and dry air at high altitude level of 36000 ft above MSL. It is observed that high shock velocities eventually results in dissociation of gaseous molecules and formation of new gaseous species which has been quantified in the manuscript.

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