Low-temperature and high-voltage lithium-ion battery enabled by localized high-concentration carboxylate electrolytes

TT Feng and GZ Yang and S Zhang and ZQ Xu and HP Zhou and MQ Wu, CHEMICAL ENGINEERING JOURNAL, 433, 134138 (2022).

DOI: 10.1016/j.cej.2021.134138

Using localized high-concentration electrolytes (LHCEs), which have high oxidation resistance and low viscosity, in high-voltage lithium-ion batteries can facilitate the low-temperature operation of the batteries. In this study, a new short-chain fluorinated diluent 1,1,2,2-tetrafluoroethyl methyl ether is used to prepare a methyl acetate-based LHCE that shows good stability against a LiNi0.5Mn1.5O4 (LNMO) cathode. Furthermore, an LNMO parallel to Li battery (3-4.9 V vs. Li/Li+) with the LHCE shows good cycling stability at mom temperature at 1C. Owing to the excellent low-temperature performance of the LHCE, the battery can discharge 80.85% of its mom temperature capacity at 0.2C at the temperature of -50 degrees C and show reversible charge/discharge behavior at 0.1C at the temperature of -40 degrees C. In this study, LHCEs are successfully used to realize a high-voltage battery that could operate with a relatively high current density (>= 0.1C) at a low temperature (-50 degrees C).

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