Revealing nanoscale strain mechanisms in ion-irradiated multilayers

N Daghbouj and HS Sen and M Callisti and M Vronka and M Karlik and J Duchon and J Cech and V Havranek and T Polcar, ACTA MATERIALIA, 229, 117807 (2022).

DOI: 10.1016/j.actamat.2022.117807

Tailoring interfaces is a powerful way of reducing the accumulation of radiation defects. Understanding strain evolution induced by ion bombardment in nuclear materials with high interface density is crucial for next-generation reactors since induced defects are responsible for volumetric swelling and catastrophic failure. X-ray and selected-area diffraction patterns (SADPs) measurements reveal, after Cu implantation, that a relatively high out-of-plane strain is created in thin Zr/Nb-6 multilayers, while thick Zr/Nb96 is barely distorted. The absence of layer deformation in Zr/Nb-96 is explained by local TEM strain mapping showing the presence of two oppositely distorted regions (inner and interface-affected regions) within one layer producing only a small overall strain, whereas the whole individual layers of Zr/Nb-6 are affected by the interface manifesting high strain. Using MD simulations, the types of defects responsible for layer distortion are identified. The opposite distortion within the layer is attributed to the inequality of the defect flux from the inner to interface-affected region due to the difference in migration energy barriers of the point defects. Moreover, the interface sink efficiency (defect annihilation) is determined for Zr/Nb as an illustration which provides a strategy for designing new derivate structures of multilayers with high radiation damage resistance. (c) 2022 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

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