Electropumping of water in nanochannels using non-uniform electric fields

YX Xu and JB Xu and HZ Liu and C Yang, CHEMICAL ENGINEERING SCIENCE, 267, 118325 (2023).

DOI: 10.1016/j.ces.2022.118325

Pumping fluids at the nanoscale is of fundamental importance to nanofluidic systems. We perform molecular dynamics simulations and provide the extended Navier-Stokes (ENS) equation to prove the electropumping possibility of using non-uniform electric fields to induce the continuous and unidirec-tional net flow of water confined in nanochannels. The net flow can be seen as a result of the combined effects of the unidirectional orientation of water molecules and the net force induced by the electric field intensity difference between O and H atoms in a water molecule. Higher net flow rates can be achieved by enhancing the electric field intensity gradients through the characteristics parameter adjustment of external electric fields. Importantly, the electropumping is more effective than the pressure- driven flow due to the ordered arrangements of water molecules in electric fields. The ENS equation proposed is more applicable at the flow field with high order degree of water molecules.(c) 2022 Elsevier Ltd. All rights reserved.

Return to Publications page