Plasticity Improvement in a Co-Rich Co₄₀Fe₂₅Cr₂₀Ni₁₅ High- Entropy Alloy via Al Alloying

YX Li and Y Chen and RK Nutor and N Wang and QP Cao and XD Wang and DX Zhang and JZ Jiang, MATERIALS, 16, 1149 (2023).

DOI: 10.3390/ma16031149

The mechanical properties of high-entropy alloys (HEAs) can be regulated by altering the stacking fault energy (SFE) through compositional modulation. The Co-rich HEAs, exhibiting deformation twinning and even strain-induced martensitic transformation at room temperature, suffer from insufficient ductility at high strength. In this work, we developed Co-rich (Co40Fe25Cr20Ni15)(100-x)Al-x (x = 0 and 5 at.%) HEAs and investigated their tensile behaviors at room temperature. The addition of Al resulted in a massive improvement in the strength-ductility product, even at similar grain sizes, and also altered the fracture mode from quasi-cleavage to ductile dimple fracture. Interestingly, both alloys were deformed by mechanical twinning, which was also verified by molecular dynamics (MD) simulations. The MD simulations revealed the SFE increased upon Al addition; however, the slip energy barrier was reduced, which favored the mobility of dislocations and twinning propensity to prolong strain hardening. The present findings provide further insights into the regulation of mechanical properties of HEAs by Al-alloying.

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