Does supercooled water retain its universal nucleation behavior under shear at high pressure?

S Srirangam and M Bhendale and JK Singh, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 25, 21528-21537 (2023).

DOI: 10.1039/d3cp01605f

Understanding the nucleation of homogeneous flow systems at high pressures is vital in protein crystallization and cryopreservation, where high pressure prevents the freezing of biological samples. This study examines the behavior of ice nucleation under shear at various pressures and explores the universal nucleation behavior of the sheared systems applied to supercooled water at higher pressures. In this study, the nucleation rates for the TIP4P/Ice model via a seeding method based on extended classical nucleation theory (CNT) are computed at pressures of 1, 100, 500, 700, and 1000 bar and a constant temperature of 240 K. Using extended CNT with explicitly embodying the shear rate, we analyzed the dependence of pressure on the transport and thermodynamic properties. In line with previous studies, we observed that & UDelta;& mu;(liq-ice) and viscosity decrease while diffusivity increases with an increase in pressure. Furthermore, we showed that the dependence of the nucleation rate on shear at higher pressure is non-monotonic, with the maximum at optimal shear rates between 10(7) and 10(8) s(-1). Our results demonstrate a non-monotonic pressure dependence of the optimal shear rates, which could originate from a violation of the Stokes- Einstein relation.

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